Wireless syncing of iDevices is one of the most exciting feature out of 200+ new features of iOS 5. So, through the guide below you will learn how to sync your iPhone, iPod Touch or iPad over Wi-Fi while you are running iOS 5.
Enable Wireless Syncing from iTunes
Requirements:
- Update iPhone, iPod Touch or iPad to iOS 5
- Download and install iTunes 10.5 for Windows or Mac
Step-1
Attach your iDevice to computer via USB and open iTunes
Step-2
In the left pane of iTunes select your iDevice under “Devices”
Click “Summary” tab, and check the box followed by the option “Sync with this iPhone (iPad or iPod touch) over Wi-Fi” and “Apply” changes

Now, your iDevice will start auto syncing to your computer whenever both of your devices will be on same wi-fi internet connection.
Start Wireless Syncing from Device
Step-1
Tap on “Settings” from Springboard
Step-2
Navigate to “General” > “iTunes Wi-Fi Sync” and tap “Sync Now” button and that’s it